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- W1554764162 abstract "We describe the vapor-phase reaction (at room temperature and 40−45% relative humidity) of silicon wafers with the azeotropic mixture of trimethylchlorosilane and tetrachlorosilane. Water contact angle analysis indicates that surfaces become nearly perfectly hydrophobic (θA/θR ≥176°/≥176°) after 2 min of reaction. SEM analysis at various reaction times shows the growth of nanofilaments with diameters of ∼30 nm. X-ray photoelectron spectroscopy of oxidized titanium surfaces that were exposed to the azeotrope vapor indicates that the product is derived from a ∼10:1 ratio of SiCl4 and (CH3)3SiCl. A mechanism for filament growth is proposed." @default.
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- W1554764162 date "2007-12-19" @default.
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- W1554764162 title "(CH<sub>3</sub>)<sub>3</sub>SiCl/SiCl<sub>4</sub> Azeotrope Grows Superhydrophobic Nanofilaments" @default.
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- W1554764162 doi "https://doi.org/10.1021/la7025297" @default.
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