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• W1554949384 abstract "Abstract The anodic oxidation of polycrystalline UO 2 has been studied in neutral Na 2 SO 4 solution (6 E E ≅+0.3 V), a thin film (t molecular layers) of UO 2+ x ( x ≤0.25) was formed. At slightly more positive potentials and longer times (1 t 3 O 7 grew on top of this UO 2+ x base layer. For potentials >+0.1 V, dissolution as U(VI) occurred, and for E =+0.3 V the surface film was transformed gradually to U 2 O 5 (≅1 h) and eventually to U 3 O 8 ( t t16 h). For E ≥+0.4 V a film of UO 3 · z H 2 O precipitated on the electrode surface in the absence of stirring. Also some dissolution of the U 2 O 5 film occurred due to a decrease in the local pH at the electrode surface. Both the precipitation and the film dissolution were prevented by stirring." @default.
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• W1554949384 date "1983-07-01" @default.
• W1554949384 modified "2023-09-26" @default.
• W1554949384 title "Anodic oxidation of UO2" @default.
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• W1554949384 doi "https://doi.org/10.1016/s0022-0728(83)80204-6" @default.
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