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• W1555087255 startingPage "145" @default.
• W1555087255 abstract "Installation of substrate-bound catalyst-directing phosphine groups allows for efficient substrate control of all aspects of reaction selectivity in the course of the industrially important hydroformylation reaction. In particular, the ortho-diphenylphosphanylbenzoyl (o-DPPB) group has proved to be a highly efficient and practical directing group for controlling regioselectivity and diastereoselectivity of a range allylic and homoallylic alcohol derivatives. A chiral variant, the o-DPPF directing group, enables a desymmetrizing hydroformylation of prochiral dialkenyl- and diallylcarbinols to give substrates with two stereocenters in enantiomerically pure form. Incorporation of the hydroformylation as part of sequential processes is possible and has led to the development of synthetically appealing multiple carbon–carbon and carbon–heteroatom bond formations." @default.
• W1555087255 created "2016-06-24" @default.
• W1555087255 creator A5067624195 @default.
• W1555087255 date "2007-01-01" @default.
• W1555087255 modified "2023-09-23" @default.
• W1555087255 title "Directed Rhodium-Catalyzed Hydroformylation of Alkenes" @default.
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• W1555087255 doi "https://doi.org/10.1007/3418_2007_067" @default.
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