Matches in SemOpenAlex for { <https://semopenalex.org/work/W1555491967> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W1555491967 abstract "Functionalization of metal complexes by introduction of functional groups has been recognized to be important toward the development of further functionality of metal complexes, including ion sensing, molecular recognition, and selective catalysis. Convergence of functional groups into certain direction and appropriate spatial arrangement can be achieved by coordination of metal ions to ligands with those groups to perform novel functions that cannot be achieved by organic ligand molecules for themselves. This strategy allows us to access multifunctional molecules more easily than that with well-designed organic molecules in terms of synthetic availability. Ruthenium complexes bearing chelating pyridylamine ligands are robust enough to hold those ligands in the coordination spheres for the convergence of functional groups attached to the ligands and to maintain their appropriate spatial geometry. We have used tris(2pyridylmethyl)amine (TPA) and its derivatives which coordinate to the ruthenium ion as tetradentate ligands. Introduction of functional groups to the 6-position of pyridine rings of TPA can provide additional functionality for ruthenium-TPA complexes (Figure 1). The concept, i.e., the introduction of amide groups at the 6-positions of pyridine rings in TPA, has been originally introduced by Masuda and coworkers to construct a hydrophobic and sterically protected environment in copper complexes by using pivaloylamide groups (Harata et al., 1994, 1995, 1998; Wada et al., 1998). They have succeeded in a number of important metal complexes in bioinorganic chemistry. Inspired by their works, we have developed our concept to functionalize ruthenium-TPA complexes by introducing various functional groups via amide linkages. In our case, the ruthenium complexes bearing trisubstituted TPA is not suitable for functionalization due to its large steric crowding. Therefore we have applied bisamide and monoamide-TPA as ligands. In this chapter, we will present an overview of a chemistry of ruthenium complexes bearing bisamide-TPA and monoamide-TPA as ligands and their characteristics." @default.
- W1555491967 created "2016-06-24" @default.
- W1555491967 creator A5064821910 @default.
- W1555491967 creator A5071318063 @default.
- W1555491967 date "2011-12-16" @default.
- W1555491967 modified "2023-10-01" @default.
- W1555491967 title "Ruthenium(II)-Pyridylamine Complexes Having Functional Groups via Amide Linkages" @default.
- W1555491967 cites W1967422520 @default.
- W1555491967 cites W1967555298 @default.
- W1555491967 cites W1975015944 @default.
- W1555491967 cites W1995106427 @default.
- W1555491967 cites W2018201877 @default.
- W1555491967 cites W2020007375 @default.
- W1555491967 cites W2039893089 @default.
- W1555491967 cites W2044117743 @default.
- W1555491967 cites W2047551398 @default.
- W1555491967 cites W2054897769 @default.
- W1555491967 cites W2061733050 @default.
- W1555491967 cites W2071386921 @default.
- W1555491967 cites W2072369632 @default.
- W1555491967 cites W2097682324 @default.
- W1555491967 cites W2142199780 @default.
- W1555491967 cites W2142594455 @default.
- W1555491967 cites W2163830195 @default.
- W1555491967 doi "https://doi.org/10.5772/31115" @default.
- W1555491967 hasPublicationYear "2011" @default.
- W1555491967 type Work @default.
- W1555491967 sameAs 1555491967 @default.
- W1555491967 citedByCount "0" @default.
- W1555491967 crossrefType "book-chapter" @default.
- W1555491967 hasAuthorship W1555491967A5064821910 @default.
- W1555491967 hasAuthorship W1555491967A5071318063 @default.
- W1555491967 hasBestOaLocation W15554919671 @default.
- W1555491967 hasConcept C116569031 @default.
- W1555491967 hasConcept C161790260 @default.
- W1555491967 hasConcept C170493617 @default.
- W1555491967 hasConcept C178790620 @default.
- W1555491967 hasConcept C185592680 @default.
- W1555491967 hasConcept C201194858 @default.
- W1555491967 hasConcept C21951064 @default.
- W1555491967 hasConcept C2777332933 @default.
- W1555491967 hasConcept C2778439535 @default.
- W1555491967 hasConcept C2779485729 @default.
- W1555491967 hasConcept C32909587 @default.
- W1555491967 hasConcept C521977710 @default.
- W1555491967 hasConcept C544153396 @default.
- W1555491967 hasConcept C55493867 @default.
- W1555491967 hasConcept C555196967 @default.
- W1555491967 hasConcept C68913812 @default.
- W1555491967 hasConcept C71240020 @default.
- W1555491967 hasConceptScore W1555491967C116569031 @default.
- W1555491967 hasConceptScore W1555491967C161790260 @default.
- W1555491967 hasConceptScore W1555491967C170493617 @default.
- W1555491967 hasConceptScore W1555491967C178790620 @default.
- W1555491967 hasConceptScore W1555491967C185592680 @default.
- W1555491967 hasConceptScore W1555491967C201194858 @default.
- W1555491967 hasConceptScore W1555491967C21951064 @default.
- W1555491967 hasConceptScore W1555491967C2777332933 @default.
- W1555491967 hasConceptScore W1555491967C2778439535 @default.
- W1555491967 hasConceptScore W1555491967C2779485729 @default.
- W1555491967 hasConceptScore W1555491967C32909587 @default.
- W1555491967 hasConceptScore W1555491967C521977710 @default.
- W1555491967 hasConceptScore W1555491967C544153396 @default.
- W1555491967 hasConceptScore W1555491967C55493867 @default.
- W1555491967 hasConceptScore W1555491967C555196967 @default.
- W1555491967 hasConceptScore W1555491967C68913812 @default.
- W1555491967 hasConceptScore W1555491967C71240020 @default.
- W1555491967 hasLocation W15554919671 @default.
- W1555491967 hasLocation W15554919672 @default.
- W1555491967 hasOpenAccess W1555491967 @default.
- W1555491967 hasPrimaryLocation W15554919671 @default.
- W1555491967 hasRelatedWork W1486738255 @default.
- W1555491967 hasRelatedWork W2013594223 @default.
- W1555491967 hasRelatedWork W2037906407 @default.
- W1555491967 hasRelatedWork W2078259680 @default.
- W1555491967 hasRelatedWork W2164136297 @default.
- W1555491967 hasRelatedWork W2275451239 @default.
- W1555491967 hasRelatedWork W2747465230 @default.
- W1555491967 hasRelatedWork W2761840320 @default.
- W1555491967 hasRelatedWork W2766281980 @default.
- W1555491967 hasRelatedWork W2777171685 @default.
- W1555491967 hasRelatedWork W2785515262 @default.
- W1555491967 hasRelatedWork W2888733140 @default.
- W1555491967 hasRelatedWork W2948357821 @default.
- W1555491967 hasRelatedWork W2950022417 @default.
- W1555491967 hasRelatedWork W2951495747 @default.
- W1555491967 hasRelatedWork W2953148866 @default.
- W1555491967 hasRelatedWork W3087768381 @default.
- W1555491967 hasRelatedWork W3155878145 @default.
- W1555491967 hasRelatedWork W3201109681 @default.
- W1555491967 hasRelatedWork W2161776893 @default.
- W1555491967 isParatext "false" @default.
- W1555491967 isRetracted "false" @default.
- W1555491967 magId "1555491967" @default.
- W1555491967 workType "book-chapter" @default.