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• W1555826660 abstract "The mixed-ligand complexes, [Cux(phen)yLz] (where phen stands for 1,10-phenanthroline and L for some aliphatic acids, aromatic acids, amino acids, phenols and ethylenediamine in the ratio 1:1:1 and 1:2:1) undergo two-step, diffusion-controlled, irreversible electro-reduction in 0.5 M KNO3 at the dropping mercury electrode. The double-wave nature of these complexes may be attributed to the adsorption effect of 1,10-phenanthroline. From the characteristics of the irreversible wave, the rate constant kf, for each complex has been calculated at its formal potential. The driving force for the formation of ternary systems has been analysed. The parent complex, [Cu(phen)] is found to show a discriminating nature towards the incoming secondary ligand. Additional stability effects compared to such systems with 2,2′-bipyridyl as the parent ligand have been explained on the basis of comparatively greater π-effects of 1,10-phenanthroline. Such effects are found to become more pronounced, due to the cooperative effect, if the secondary ligand also has a π-system." @default.
• W1555826660 created "2016-06-24" @default.
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• W1555826660 date "1982-12-01" @default.
• W1555826660 modified "2023-10-02" @default.
• W1555826660 title "π-Acid effect on electrode behaviour of ternary complexes in solution" @default.
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• W1555826660 doi "https://doi.org/10.1016/0302-4598(82)89001-6" @default.
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