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• W1555873886 abstract "The structural phase change arising from the cooperative Jahn-Teller effect has been studied by Raman scattering and optical birefringence methods in the mixed crystals TbpGd1-pVO4 and DypY1-pVO4 with p varying from one to zero. The introduction of Gd and Y dilutes the active components causing the phase change, resulting in a reduction of the transition temperature TD(p). Varying p varies the splitting of Eg phonons below Tp(p) and also the energy of low-lying collective electronic excitations. The Tb system shows unique behaviour with p=0.365; a transition from tetragonal to orthorhombic symmetry occurs at 8.5K but the crystal reverts to tetragonal symmetry below 2.3K. The effect in the Tb system can be explained by mean-field theory. The Dy compounds are explained using series expansion and modified mean-field methods." @default.
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• W1555873886 date "1974-09-07" @default.
• W1555873886 modified "2023-10-18" @default.
• W1555873886 title "Cooperative Jahn-Teller effects in the mixed crystals Tb_pGd_1-pVO₄and Dy_pY_1-pVO₄" @default.
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• W1555873886 doi "https://doi.org/10.1088/0022-3719/7/17/022" @default.
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