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- W1555877891 abstract "Abstract The ion—molecule reactions of both parent and fragment ions in C2HF3 and C2F4 have been observed. Absolute rate constants have been measured for the parent ion reactions in both systems and in the mixed system. In each case, the only condensation reaction involves elimination of the ·CF3 radical although other reaction channels are thermodynamically allowed. The rates of the CF3 elimination reactions vary from 0.3 to 5.6 X 10−11 cm3 molecule−1 sec−1. Substantial decreases in the rates are observed at low pressures. This effect is attributed to internal energy in the reactant ions. The reversible charge transfer reaction was also observed in the mixed system. The equilibrium constant for this reaction has been measured yielding ΔGD = 0.023 ± 0.001 eV as the free energy of the charge exchange (C2F4⨥ → C2HF3⨥). This value agrees well with previously determined differences in ionization potentials. Thermodynamic implications are discussed for the fragment ion reactions." @default.
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- W1555877891 date "1973-04-01" @default.
- W1555877891 modified "2023-09-24" @default.
- W1555877891 title "ICR mass spectra of fluoroalkenes" @default.
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- W1555877891 doi "https://doi.org/10.1016/0020-7381(73)80003-8" @default.
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