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• W155595340 abstract "High pressure - high temperature conditions have been used for the synthesis of new mixed transition metal oxides. The following phase transitions were investigated: hausmanite to CaMn204-type in Mn 3 O 4 ; spinel to CaFe 2 O 4 -type in CdCr 2 O 4 ; warwickite to olivine in NiFeB04; VFeO 4 to wolframite in VFeO 4 ; brannerite to columbite in MV 2 O 6 compounds with M 2+ = Ni 2+ , Mg 2+ , Co 2+ , Zn 2+ , Cd 2+ ; boehmite and NaHF 2 -type to diaspore and InOOH-type for the oxyhydroxides MOOH with M 3+ = Fe 3+ , Cr 3+ , Mn 3+ , Co 3+ , Ni 3+ , V 3+ . New compounds have also been synthesized from two phases regions namely: -CO 2 O 3 with the corundum structure; this metastable oxide prepared at 80 kbar of oxygen pressure undergoes at 400°C (at room pressure) a phase transition to another corundum phase of lower density. The transition is due to a low-spin to high-spin transition of Co 3+ cations." @default.
• W155595340 created "2016-06-24" @default.
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• W155595340 date "1974-01-01" @default.
• W155595340 modified "2023-09-23" @default.
• W155595340 title "SYNTHESIS OF NEW DENSE PHASES OF MIXED TRANSITION METAL OXIDES UNDER HIGH PRESSURE AND HIGH TEMPERATURE CONDITIONS" @default.
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• W155595340 doi "https://doi.org/10.1016/b978-0-408-70578-3.50006-3" @default.
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