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- W1556023044 abstract "The reaction of anthracene with SO2 in the presence of benzoyl peroxide using n-heptane as solvent, yielded anthronyl phenyl sulfone, oligomers (anthracene polysulfones), diphenyl disulfone, benzenesulfonic acid, anthraquinone, benzoic acid and benzene. If benzene was used as solvent, the formation of the sulfones mentioned above was not observed, and instead the reaction yielded 9,10-dibenzoyloxyanthracene, dianthrone, anthraquinone, benzoic acid and a trace of benzene-sulfonic acid. These results have been interpreted in terms of a C-T complex1 of anthracene-sulfur dioxide, since the sulfones are readily formed in a solvent such as n-heptane which does not interact with SO2, whereas the formation of the sulfones is diminished in a solvent such as benzene due to its interaction with SO2.2 As in the reaction of SO2 with benzoyl peroxide using n-heptane as a solvent, diphenyl disulfone, benzenesulfonic acid, benzoic acid, benzene, phenyl benzoate and diphenyl disulfide were isolated; the yields of diphenyl disulfone, benzenesulfonic acid and diphenyl disulfide being derived from the phenylsulfonyl radical were larger than those obtained from the reaction with anthracene, the phenyl radical readily reacts with SO2 in the absence of anthracene, but the formation of the phenylsulfonyl radical is diminished in the presence of anthracene. And these results might be interpreted in terms of the interaction of anthracene with SO2 rather than with the phenyl radical, because phenylanthracene derivatives did not form but some anthracene sulfone was obtained." @default.
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- W1556023044 date "1967-01-01" @default.
- W1556023044 modified "2023-09-23" @default.
- W1556023044 title "The reaction of anthracene with sulfur dioxide in the presence of benzoyl peroxide" @default.
- W1556023044 cites W1979139109 @default.
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- W1556023044 doi "https://doi.org/10.1016/s0040-4020(01)82576-x" @default.
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