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- W1556043827 abstract "A mathematical model is proposed for describing metal discharge-ionization processes involving interaction with electrode surface. Use is made of the concept of two energetic states of the metal deposited on electrode surface, differing by the magnitude of Gibb's free energy (ΔG0). Calculated values are given for the electrochemical equivalents of the metal in the first (q1) and second (q2) energetic states as a function of ΔG0, electrode potential, duration of deposition, concentration of discharging ions. It is shown that the conditions governing the cathode process determine the character of the stripping polarogram (one or two current peaks), and that a linear correlation exists between the difference of peak potentials and the value of Gibb's free energy." @default.
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- W1556043827 date "1979-05-01" @default.
- W1556043827 modified "2023-10-14" @default.
- W1556043827 title "Discharge-ionization of metals on an indifferent electrode" @default.
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- W1556043827 doi "https://doi.org/10.1016/s0022-0728(79)80406-4" @default.
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