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- W1556077545 abstract "Abstract ( t BuC 5 H 4 )TiCl 2 (O-2,6- i Pr 2 C 6 H 3 ) ( 2 ) exhibited relatively high catalytic activity for syndiospecific polymerization of styrene at 25 °C if both [PhMe 2 NH]B(C 6 F 5 ) 4 and a mixture of Al i Bu 3 /Al( n -C 8 H 17 ) 3 were used as the cocatalyst. Effects of both organoaluminum and organoboron compounds were explored, and the effect of cocatalyst was different from that observed in 1-hexene polymerization catalyzed by Cp*TiCl 2 (O-2,6- i Pr 2 C 6 H 3 ) ( 1 ). Resultant syndiotactic polystyrene possessed narrow molecular weight distribution under the optimized conditions, and the M w values were unchanged during the time course." @default.
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- W1556077545 date "2003-06-01" @default.
- W1556077545 modified "2023-09-26" @default.
- W1556077545 title "Syndiospecific styrene polymerization by (tert-BuC5H4)TiCl2(O-2,6- Pr2C6H3) – borate catalyst system" @default.
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- W1556077545 doi "https://doi.org/10.1016/s1566-7367(03)00052-9" @default.
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