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- W1556289969 abstract "The iodine species formed either by adding hypochlorite to a basic iodide solution or by adding triiodide to sodium hydroxide, was identified as hypoiodite ion. The absorption spectrum of IO- was investigated in the wavelength range from 450 mμ to 280 mμ. The kinetics of the reaction I- + ClO- = IO- + Cl- was studied spectrophotometrically in alkaline solution. The forward rate law was found to be d(IO-)/dt = k(I-)(ClO-)/OH-. At 25 C and an ionic strength of 1.00 M, k is 61 ± 3 sec-. It was found spectrophotometrically that for certain ratios of the initial iodide to hydroxide concentrations, there was evidence of the presence of I3-, I2OH-, and I2O2- along with IO-. The equilibrium constants between IO- and these three species were evaluated by a graphical method. The formal potential of the cell: Pt:H2:1 M NaOH : 1M NaOH, KI, NaIO : Au was found to be 1.297 v at 25 C. The equilibrium constant, K2 = (I3-)(OH-)-2/(IO-)(I-)2, of the reaction IO- + 2I- + H2O ⇌ I3- + 2OH- calculated from emf measurements agreed well with that from spectrophotometric measurements. The ionization constant of HOI was calculated to be 2.3 x 10-11 at 25 C." @default.
- W1556289969 created "2016-06-24" @default.
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- W1556289969 date "1958-06-02" @default.
- W1556289969 modified "2023-10-14" @default.
- W1556289969 title "Chemistry of +1 iodine in alkaline solution" @default.
- W1556289969 doi "https://doi.org/10.2172/932596" @default.
- W1556289969 hasPublicationYear "1958" @default.
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