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- W1556485616 abstract "The investigation of the mechanism of the electrochemical oxidation of uranium(IV) in sodium bicarbonate solutions is described. The investigation of the electrochemical reaction was carried out using the chronopotentiometric technique and is confined to concentrations of uranium and bicarbonate, at which the former is soluble and stable (1–4 mM of U4+ and 0.4–1.0 M NaHCO3). The electrochemical oxidation is an irreversible (β=0.7±0.02), two-electron transfer reaction with an Eτ/4=−0.17±0.01 V vs. SCE for 1 mM uranium(IV) in 1 M sodium bicarbonate. Evidence is given for chemical kinetic steps, preceding the electrochemical reaction, dependent both on the concentration of uranium and of carbonate. A hypothesis of a “deactivation” mechanism, involving competing association-dissociation reactions, is advanced." @default.
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- W1556485616 date "1968-11-01" @default.
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- W1556485616 title "The electrochemical oxidation of uranium(IV) in sodium bicarbonate solutions" @default.
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- W1556485616 doi "https://doi.org/10.1016/s0022-0728(68)80125-1" @default.
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