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- W1557777260 abstract "The stabilities of the Mn2+-, Co2+-, Ni2+-, Cu2+- and Zn2+-complexes with 2-(carboxymethyl)glutaric acid (2) and cis,cis-1,3,5-cyclohexanetricarboxylic acid (3) were measured potentiometrically at 25° and I = 0.5 (KNO3). Beside the complexes ML− protonated species MLH and MLH are also formed. Their stability constants are given in Table 1. A comparison between the stabilities of 2 or 3 and those of acetate, as a model for a monocarboxylate, or succinate and glutarate, as examples for dicarboxylates, indicates that in all species only one carboxylate is strongly bound whereas the second and third ones are probably not. The observation that Δlog K1 = log K − log K as well as Δlog K2 = log K − log K are practically constants with values of 0.34 ± 0.05 and 0.49 ± 0.07, respectively, for both ligands and the five metal ions studied is also in line with the proposed monodentate structures of the complexes ML−, MLH and MLH." @default.
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- W1557777260 date "1983-07-27" @default.
- W1557777260 modified "2023-09-26" @default.
- W1557777260 title "Zur Stabilität der Metallkomplexe von Methantriessigsäure undcis, cis-1,3,5-Cyclohexantricarbonsäure" @default.
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- W1557777260 doi "https://doi.org/10.1002/hlca.19830660527" @default.
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