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- W1558366914 abstract "A steady-state fluorescence (SSF) technique was used for studying the dissolution of UV-cured polymer films. These films are formed from poly(methyl methacrylate) (PMMA) chains labelled with pyrene, which was introduced as a fluorescence probe to monitor the dissolution processes. The PMMA films of various ethylene glycol dimethacrylate (EGDM) contents, cured by ultraviolet (UV) radiation, were dissolved in chloroform–heptane (20 : 80, v/v) mixtures. Dissolution of the films was monitored in real-time by the change in pyrene fluorescence intensity, IP, in the solvent mixture. It was observed that the maximum pyrene intensity, IP∞, increased above a critical EGDM content, which was attributed to the formation of a percolation cluster, i.e. UV-cured films hardly dissolve above this critical EGDM content in the film. Desorption rates, Dd, were measured for films prepared with various EGDM contents. Copyright © 2002 John Wiley & Sons, Ltd." @default.
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- W1558366914 date "2002-05-23" @default.
- W1558366914 modified "2023-10-17" @default.
- W1558366914 title "Dissolution of UV-cured polymeric films: a fluorescence study" @default.
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- W1558366914 doi "https://doi.org/10.1002/sia.1413" @default.
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