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- W1558687082 abstract "Abstract The photosensitized oxygenation of 4,6-di-t-butylresorcinol (1) and its methyl ethers 8 and 10 in methanol have been examined. Resorcinol (1) affords ketoester 2 and lactone 3. Photosensitized oxygenation of monoethyl ether 8 and dimethyl ether 10 gives hydroperoxide 9 and epoxy-ketone 11, respectively; participation of singlet oxygen in these reactions is demonstrated. A mechanism involving 1,4-cycloaddition of singlet oxygen to the aromatic nucleus is proposed for the formation of 9 and 11, but a mechanism involving a phenoxy radical intermediate 14 for the formation of 2 and 3." @default.
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- W1558687082 date "1972-01-01" @default.
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- W1558687082 title "Photoinduced reactions—LVIII" @default.
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- W1558687082 doi "https://doi.org/10.1016/s0040-4020(01)88932-8" @default.
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