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- W1558906726 abstract "The reaction of metastable Mo(5S2s1d5) with methane was studied using the method of crossed molecular beams. Angular and velocity distributions of the MoCH2 products were obtained at relative collision energies of 7.2 and 13.0 kcal/mol. The center-of-mass MoCH2 angular distributions exhibited forward–backward symmetry, consistent with a mechanism involving C–H bond insertion forming HMoCH3 followed by H2 elimination. The potential energy barrier for insertion of Mo(5S2s1d5) into CH4 is less than or equal to 7.2 kcal/mol." @default.
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- W1558906726 date "1998-02-15" @default.
- W1558906726 modified "2023-09-26" @default.
- W1558906726 title "Crossed beams study of C-H bond activation: Mo(5S2)+CH4→MoCH2+H2" @default.
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- W1558906726 doi "https://doi.org/10.1063/1.475658" @default.
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