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- W1559389627 abstract "It was found that synthesis gas was converted selectively to C2C4 paraffins with hybrid catalysts composed of a physically mixed methanol synthesis catalyst (PdSiO2) and Y-type zeolites. The favorable conditions were 300–350 °C and 1.0–5.1 MPa. A hybrid catalyst which contained a steamtreated high-silica Y-zeolite gave C2C4 paraffins with the selectivity higher than 85% with an almost complete lack in aromatic hydrocarbons and coke with a methane selectivity of 2% or less, while methanol conversion on the zeolite gave aromatic hydrocarbons and coke with selectivities of 30 and 11%, respectively. The chain growth probability of the hydrocarbon, αn which has been determined by ratio of the sum of Cn + 1+ hydrocarbons to the sum of Cn+ hydrocarbons decreased with increasing carbon number from 0.99 (C1) to 0.20 (C5)." @default.
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- W1559389627 date "1985-07-01" @default.
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- W1559389627 title "Synthesis gas conversion utilizing mixed catalyst composed of CO reducing catalyst and solid acid" @default.
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- W1559389627 doi "https://doi.org/10.1016/0021-9517(85)90078-8" @default.
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