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- W1559644906 abstract "The kinetic studies were conducted on the reaction between propyl propane-thiol-sulfinate (PrSSOPr) or -thiolsulfonate (PrSSO2Pr) and 1-cysteine. The reactions were shown by the following equations. PrSSOPr+CySH→CySSPr+(PrSOH) 2(PrSOH)→PrSSOPr+H2O and PrSSO2Pr+CySH→CySSPr+PrSO2H The studies were carriepd out at an acidic pH because of the very fast rates of these reactions. The reaction species of cysteine was proved to be the protonated S-anion, RN+H3·S-. The values of the enthalpy of activation and the entropy of activation were calculated to be 8.4 kcal/mole, -15.1 e.u. for PrSSOPr and 2.9 kcal/mole, -19.2 e. u. for PrSSO2Pr." @default.
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- W1559644906 date "1971-01-01" @default.
- W1559644906 modified "2023-10-04" @default.
- W1559644906 title "Thiamine Derivatives of Disulfide Type. XII. Kinetic Studies on the Reaction between Propyl Propane-Thiolsulfinate or -Thiolsulfonate and Cysteine" @default.
- W1559644906 doi "https://doi.org/10.1248/cpb.19.2433" @default.
- W1559644906 hasPublicationYear "1971" @default.
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