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- W1559922839 abstract "LiAlH(O-tBu)3 reduction of 2-decalones and 5α-cholestane-3-ones, unsubstituted or β-substituted by axial or equatorial CN or CH3 groups show relative rates of attack on both sides of cyanodecalones and decalone which can be interpreted in terms of orbital control by axial C-H bonds α and α' to the carbonyl group. With axial methyl groups, the stereoselectivity depends on unequal 1,3 diaxial interactions which induce ring flattening favouring this orbital control." @default.
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- W1559922839 date "1979-01-01" @default.
- W1559922839 modified "2023-10-09" @default.
- W1559922839 title "Stereochimie—li controle orbitalaire de la stereochimie des reactions—ii" @default.
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- W1559922839 doi "https://doi.org/10.1016/s0040-4020(01)93710-x" @default.
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