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- W1560432847 abstract "Abstract The i.r. and Raman spectra of some aliphatic thioketones have been investigated in the range 1000–1700 cm −1 . An absorption band is assigned to the stretching vibration of the thiocarbonyl group in the range 1244–1270 cm −1 . The thiocarbonyl frequencies are correlated with the sum of the Taft parameters for the substituents of the group. The i.r. intensity of this band is 7,5·10 3 cm −2 mol −1 1· +1 for the propanethione and approximates closely to 2,5·10 3 cm −2 mol −1 1· +1 for the other thioketones. In the Raman spectrum, the thiocarbonyl band is very strong and polarized, the depolarization factor approximates very closely to 0,2." @default.
- W1560432847 created "2016-06-24" @default.
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- W1560432847 date "1972-04-01" @default.
- W1560432847 modified "2023-09-24" @default.
- W1560432847 title "Contribution à l'étude de la vibration de valence du thiocarbonyle par spectroscopie I.R." @default.
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- W1560432847 doi "https://doi.org/10.1016/0584-8539(72)80048-5" @default.
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