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- W1560769857 abstract "The photochemical reaction of tricarbonyl-η6-1,3,5-cycloheptatriene-chromium(0) (I) with tricyclo[6.3.0.02,7]undeca-3,5-diene (II) in n-pentane at 248 K yields the [4 + 6]-cycloadduct tricarbonyl-η6-pentacyclo[7.6.2.110,15.02,8.03,7]octadeca-11,13,16-triene-chromium(0) (III). Detachment of the pentacyclic triene ligand from chromium can be achieved with trimethylphosphite. The constitutions of complex III and of the pentacyclic hydrocarbon IV were determined by spectroscopic means. Die photochemische Reaktion von Tricarbonyl-η6-1,3,5-cycloheptatrien-chrom(0) (I) mit Tricyclo[6.3.0.02,7]undeca-3,5-dien (II) in n-Pentan bei 248 K ergibt das [4 + 6]-Cycloaddukt Tricarbonyl-η6-pentacyclo[7.6.2.110,15.02,8.03,7]-octadeca-11,13, 16-trien-chrom(0) (III). Mit Trimethylphosphit gelingt die Ablösung des pentacyclischen Trienliganden vom Chrom. Die Konstitutionen des Komplexes III und des pentacyclischen Kohlenwasserstoffes IV wurden mit spektroskopischen Mitteln bestimmt." @default.
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- W1560769857 date "1985-09-01" @default.
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- W1560769857 title "Photochemische reaktionen von übergangsmetall-olefin-komplexen" @default.
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- W1560769857 doi "https://doi.org/10.1016/0022-328x(85)80292-8" @default.
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