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- W1560816697 abstract "Results for the discharge capacity, discharge surface area and charge surface area elemental models are reported. Where possible, model parameters are determined from experimental studies applicable to a practical lead/acid cell. The discharge capacity model gave a capacity of 0.52 times the theoretical value. This compares well with a practical cell if the preferential discharge at the plate surface is taken into account. The simple discharge surface area model gave a linear variation with charge state between the charge and discharge surface area parameter values used. The charge surface area model showed an actual PbO2 surface area that increased steadily with charge state between the same values as the discharge surface area model. The PbSO4 surface area showed a gradual decrease until a charge state of about 0.8 and, thereafter, a rapid decrease to zero. The effective PbO2 surface area followed the trend of the PbSO4 surface area. The total (PbO2 + PbSO4) surface area variation with charge state was consistent with trends shown in the limited experimental data available. Acid concentration and geometric parameter values had a negligible influence on the model results. Increasing charge current caused a small decrease in the effective PbO2 area result." @default.
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- W1560816697 date "1993-01-01" @default.
- W1560816697 modified "2023-09-26" @default.
- W1560816697 title "Three-elemental models for the positive electrode of the lead/acid cell" @default.
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- W1560816697 doi "https://doi.org/10.1016/0378-7753(93)85001-5" @default.
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