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- W1561498585 abstract "Reductive desorption of sulfuric acid formed on the carbon catalyst in flue gas desulfurization (FGD) by heating with hydrogen at 3: 200/sup 0/C converted the acid to gas-phase sulfur dioxide with a significant loss of the acid to hydrogen sulfide and elemental sulfur. These side reactions were suppressed and the temperature required for SO/sub 2/ recovery was reduced by impregnating the charcoal with aqueous CuSO/sub 4/ to 9 mg Cu per gram of carbon. Platinum-, silver-, or palladium-containing catalysts were less efficient, and manganese-, iron-, cobalt-, nickel-, and zinc-modified catalysts behaved like untreated charcoal. With metal-alumina catalysts, SO/sub 2/ desorption started at higher temperatures than with the metal-charcoal catalysts, indicating that charcoal itself has a catalytic effect. An electrochemical catalytic mechanism is proposed." @default.
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- W1561498585 date "1979-03-01" @default.
- W1561498585 modified "2023-09-28" @default.
- W1561498585 title "Reductive desorption of sulfuric acid formed on the carbon catalyst in flue gas desulfurization (FGD)" @default.
- W1561498585 hasPublicationYear "1979" @default.
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