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- W1561881030 abstract "Thermal expansion measurements have been made between 1.5K and 30K of samples of Al10V and Al10V+0.8% Ga which reveal anomalous behaviour similar to that reported by Caplin and Nicholson in the specific heat of the same samples. The anomalous expansion, which is ascribed to the volume dependence of local mode excitations is two orders of magnitude greater than the thermal expansion of other metals at these temperatures. This allows the energy of the first excited state to be obtained with greater accuracy than from the specific heat, the values being 22+or-0.3K and 8+or-0.4K when Al and Ga respectively occupy the local mode site. The expansion was found to fit the Schottky function for four equispaced non-degenerate energy levels rather better than the Einstein function assumed previously. Re-analysis of the specific heat indicates a large temperature dependence of the Debye temperature which is thought to result from hybridisation of the phonons with local modes. The Gruneisen parameters were found to be 81 for the Al mode and 85 for the Ga mode." @default.
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- W1561881030 date "1978-10-01" @default.
- W1561881030 modified "2023-09-27" @default.
- W1561881030 title "The low temperature thermal expansion of Al10V" @default.
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- W1561881030 doi "https://doi.org/10.1088/0305-4608/8/10/012" @default.
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