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- W1562009504 abstract "Highly enantiomerically enriched γ- and δ-lactams have been prepared by a simple and very efficient procedure that involves the asymmetric transfer hydrogenation of N-(tert-butylsulfinyl)iminoesters followed by desulfinylation of the nitrogen atom and spontaneous cyclization to the desired lactams during the basic workup procedure. Five- and six-membered ring lactams bearing aromatic, heteroaromatic, and aliphatic substituents have been obtained in very high yields and ee’s up to >99%. A slight modification of the procedure also allowed the preparation of ε-lactams in good yields and very high enantioselectivities. Both enantiomers of the final lactams could be prepared with equal efficiency by changing the absolute configuration of the sulfinyl chiral auxiliary." @default.
- W1562009504 created "2016-06-24" @default.
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- W1562009504 creator A5074878462 @default.
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- W1562009504 date "2013-04-05" @default.
- W1562009504 modified "2023-10-15" @default.
- W1562009504 title "Synthesis of γ-, δ-, and ε-Lactams by Asymmetric Transfer Hydrogenation of <i>N</i>-(<i>tert</i>-Butylsulfinyl)iminoesters" @default.
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- W1562009504 doi "https://doi.org/10.1021/jo400164y" @default.
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