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- W1562492548 abstract "The naturtal l-β-hydrastine (Iβ) was epimerized to l-α-hydrastine (Iα). Iα was converted to(--)-canadine (VIII), througth ophiocarpine (VIα), whereas Iβ transformed into VIII through 13-epiophiocarpine (VIβ). The absolute configration of ophiocarpine and 13-epiophiocarpine are represented by VIα(13R : 13aR) and VIβ(13S : 13aR), respectively. Accordingly, the absolute configuration of l-α-hydrastine and l-β-hydrastine are also designated as Iα (αR : 1R)and Iβ(αS : 1R). respectively." @default.
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- W1562492548 date "1964-01-01" @default.
- W1562492548 modified "2023-09-27" @default.
- W1562492548 title "The Stereochemistry of Hydrastine, Narcotine, Ophiocarpine, and their Derivatives. I. Absolute Configuration of Hydrastine and Ophiocarpine" @default.
- W1562492548 doi "https://doi.org/10.1248/cpb.12.1072" @default.
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