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• W1562495518 endingPage "435" @default.
• W1562495518 startingPage "430" @default.
• W1562495518 abstract "Abstract The facile synthesis, molecular structure, and reactivity of [Cu(C 7 H 7 NH 2 )Cl] 4 ( 1 ) towards dioxygen and derivatives is reported. The compound could easily be prepared in good yields by mixing CuCl and benzylamine under inert conditions in dichloromethane. Surprisingly this copper(I) compound, a copper(I) tetramer with Cu I ··· Cu I interactions of 2.89 Å, was formed instead of an expected cubane cluster. Oxidation reactions led to formation of μ‐oxido‐species as intermediates, however 1 did not show any catalytic activity in the activation of CH bonds. In contrast it turned out that 1 was quite stable towards oxidation. Analogous reactions with CuBr or CuI were different and neither cluster units or polynuclear copper(I) complexes were obtained." @default.
• W1562495518 created "2016-06-24" @default.
• W1562495518 creator A5020708040 @default.
• W1562495518 creator A5038561336 @default.
• W1562495518 creator A5079811691 @default.
• W1562495518 date "2014-11-03" @default.
• W1562495518 modified "2023-10-16" @default.
• W1562495518 title "Synthesis, Structure and Reactivity of the Compound [Cu(C₇H₇NH₂)Cl]₄derived from CuCl and Benzylamine (C₇H₇NH₂)" @default.
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• W1562495518 doi "https://doi.org/10.1002/zaac.201400395" @default.
• W1562495518 hasPublicationYear "2014" @default.
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