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- W1562554650 abstract "便宜地，树脂被开发了的为 monodentate chiral ligand 的固定的一个新、简单的方法。一系列使树脂不能调动的 phosphoramidite ligands 基于 BINOL 和 TADDOL 脊梁被综合了并且与胶化阶段描绘了 NMR。使不能调动的 ligands 被用于 1,3-diphenyl-2-propenyl 醋酸盐的催化 Pd 的不对称的 allylic 完化。在四 ligands 之中，支持的笨重 monodentate phosphoramidite ligand 与 ee 基于 TADDOL 脊梁负担得起 chiral 产品直到 65% ；而且，没有变换和 ee 的实质的减少，这 ligand 能在 3 次被再循环。" @default.
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- W1562554650 date "2007-01-01" @default.
- W1562554650 modified "2023-09-24" @default.
- W1562554650 title "Polymer-Supported Chiral Monodentate Phosphoramidites in Palladium-Catalyzed Allylic Alkylation Reactions" @default.
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