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- W1562646855 abstract "The structure of the superconducting copper oxychromate Tl3CCrO4)Sr8Cu4O16 has been determined from powder neutron diffraction data. This compound derives from the “1201” classical structure by an ordered substitution of CrO4 groups for thallium oxygen polyhedra showing definitively that chromium is hexavalent. The main features that characterize this original structure deal with the waving character of the [CuO2]∞ layers, and the absolute planar character of the [(TlCr),O]∞ layers. In the [(TlCr), O]∞ layers, the thallium and oxygen atoms form triple ribbons of edge-sharing TlO4 tetrahedra and TlO6 octahedra running along bia, whereas the CrO4 tetrahedra are displayed in rows running along a, but are disconnected from each other and from the other polyhedra in the layer. Two kinds of CuO6 octahedra are observed, whose distortions originate from their connection with different polyhedra along bic. The great flexibility of the two kinds of layers, and the structural analogy with copper oxycarbonates are emphasized." @default.
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- W1562646855 date "1996-05-01" @default.
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- W1562646855 title "Neutron diffraction structure determination of the superconducting copper oxychromate Tl3(CrO4)Sr8Cu4O16" @default.
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- W1562646855 doi "https://doi.org/10.1016/0921-4534(96)00239-0" @default.
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