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- W1562775040 abstract "A copolymer containing butyl methacrylate in a 10-fold excess and furan-protected maleimidopropyl methacrylate was synthesized via atom transfer radical polymerization (ATRP). Maleimide functionalities served as dienophiles for reversible crosslinking by Diels − Alder (DA) reactions. As counterpart to the linear polymer, silica − polymer core − shell nanoparticles with grafted furfuryl groups were prepared by surface-initiated ATRP. Rheological measurements during the DA reaction at 80 °C showed an increase in storage modulus due to crosslinking within the nanocomposite. DSC allowed the detection of the endothermic retro-DA reaction above 120 °C, which provided the possibility to self-heal scratches. Repeated curing/de-crosslinking was detected using UV−visible spectroscopy and revealed the reproducibility of the thermoreversible crosslinking reaction, which is a prerequisite for the self-healing mechanism. Finally, the scratch-healing abilities of the material were verified on composite films. © 2013 Society of Chemical Industry" @default.
- W1562775040 created "2016-06-24" @default.
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- W1562775040 date "2013-12-03" @default.
- W1562775040 modified "2023-09-24" @default.
- W1562775040 title "Self-healing nanocomposites from silica − polymer core − shell nanoparticles" @default.
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- W1562775040 doi "https://doi.org/10.1002/pi.4642" @default.
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