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- W1562942010 abstract "The synthesis of a series of symmetrically and asymmetrically substituted poly(diorganylsilylene-co-ethynylene)s of the general composition [R1R2Si-CC-]x (with R1 and R2 = alkyl-, alkenyl- or alkynyl-groups) was afforded by the reaction of diorganyl-dichlorosilanes with the di-Grignard reagent BrMgCCMgBr in THF at room temperature. The products, obtained in good yields, have a regular alternating arrangement of ethynylene and silylene units. They were characterized by the usual spectroscopical methods and by gel permeation chromatography. The weight and number averages Mw and Mn reflect the oligomeric character of these compounds." @default.
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- W1562942010 date "2005-07-26" @default.
- W1562942010 modified "2023-10-03" @default.
- W1562942010 title "One‐Pot Syntheses of Poly(diorganylsilylene‐ <i>co</i> ‐Ethynylene)s" @default.
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- W1562942010 doi "https://doi.org/10.1002/9783527620777.ch101b" @default.
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