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- W1562949984 abstract "Novel organometallic uranium(IV) complexes of the composition [(η5-Cp)3UIV]2[MnII(CN)4] Cp = C5H5, M = Ni or Pt) have been prepared from Cp3UCl and K2[M(CN)4] in aqueous solution. On the basis of their properties they are characterized as layered oligomeric structures involving squared arrays of both the U and M atoms within the same plane, and a presumably trigonal bipyramidal coordination of the uranium(IV) ion. Neuartige Uran(IV)-Organyle der Zusammensetzung [(η5-Cp)3UIV]2[MII(CN)4] (Cp = C5H5, M = Ni bzw. Pt) werden aus Cp3UCl und K2[M(CN)4] in Wasser dargestellt und auf Grund ihrer Eigensehaften als Oligomere im Sinne einer Schichtstruktur mit jeweils quadratisch in einer Ebene angeordneten U- und M-Atomen charakterisiert. Das Uran(IV)-Ion ist dabei vermutlich trigonal-bipyramidal koordiniert." @default.
- W1562949984 created "2016-06-24" @default.
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- W1562949984 date "1978-08-01" @default.
- W1562949984 modified "2023-10-16" @default.
- W1562949984 title "Zur chemie des tris(cyclopentadienyl)uran(IV)-kations in wässriger lösung" @default.
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- W1562949984 doi "https://doi.org/10.1016/s0022-328x(00)93544-7" @default.
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