Matches in SemOpenAlex for { <https://semopenalex.org/work/W1563368481> ?p ?o ?g. }
- W1563368481 endingPage "215" @default.
- W1563368481 startingPage "183" @default.
- W1563368481 abstract "Publisher Summary This chapter explains the intramolecular electron transfer (ET) between the charge-bearing units (M groups) of symmetrical intervalence (IV) compounds. The classical two-state Hamiltonian has been widely used by scientists. It is now accepted that ET is a tunneling process that must be treated quantum mechanically. Changing the bridge for the σ-bridged compounds discussed in this chapter requires preparation of a different bis(azo) compound. Because methylene chloride is a solvent of low dielectric constant, ion pairing occurs detectably even for rather large cations and anions. Medium effects on ET reactions of metal complexes have been recently reviewed. Solvent effects have been uniquely important in ET studies. Marcus splits the vertical reorganization energy into solvation and internal components using dielectric continuum theory. Marcus pointed out that intrinsic rate constants (those for zero driving force reactions) are the significant ones to consider for intermolecular ET reactions, and he developed a cross-rate theory to determine them. Electron hopping is unquestionably the way that really long-distance ET is achieved in nature, and is currently a topic of great interest." @default.
- W1563368481 created "2016-06-24" @default.
- W1563368481 creator A5039975547 @default.
- W1563368481 date "2006-01-01" @default.
- W1563368481 modified "2023-10-16" @default.
- W1563368481 title "Electron transfer reactions within σ- and π-bridged dinitrogen-centered intervalence radical cations" @default.
- W1563368481 cites W1510990619 @default.
- W1563368481 cites W1512361887 @default.
- W1563368481 cites W1527819304 @default.
- W1563368481 cites W1593507858 @default.
- W1563368481 cites W1601422968 @default.
- W1563368481 cites W1966377407 @default.
- W1563368481 cites W1967721937 @default.
- W1563368481 cites W1969059256 @default.
- W1563368481 cites W1969103303 @default.
- W1563368481 cites W1969846115 @default.
- W1563368481 cites W1973726513 @default.
- W1563368481 cites W1976315195 @default.
- W1563368481 cites W1976678711 @default.
- W1563368481 cites W1977184192 @default.
- W1563368481 cites W1978152525 @default.
- W1563368481 cites W1981021029 @default.
- W1563368481 cites W1984841151 @default.
- W1563368481 cites W1985075289 @default.
- W1563368481 cites W1985851708 @default.
- W1563368481 cites W1987935734 @default.
- W1563368481 cites W1992128155 @default.
- W1563368481 cites W1993104687 @default.
- W1563368481 cites W2001270915 @default.
- W1563368481 cites W2002817145 @default.
- W1563368481 cites W2003196230 @default.
- W1563368481 cites W2004409742 @default.
- W1563368481 cites W2006377494 @default.
- W1563368481 cites W2007281955 @default.
- W1563368481 cites W2007679907 @default.
- W1563368481 cites W2008221418 @default.
- W1563368481 cites W2009576792 @default.
- W1563368481 cites W2010747249 @default.
- W1563368481 cites W2012403484 @default.
- W1563368481 cites W2013207870 @default.
- W1563368481 cites W2015051063 @default.
- W1563368481 cites W2016592851 @default.
- W1563368481 cites W2016655007 @default.
- W1563368481 cites W2019678428 @default.
- W1563368481 cites W2020664705 @default.
- W1563368481 cites W2023119502 @default.
- W1563368481 cites W2023665942 @default.
- W1563368481 cites W2024409509 @default.
- W1563368481 cites W2024552431 @default.
- W1563368481 cites W2026940298 @default.
- W1563368481 cites W2030037054 @default.
- W1563368481 cites W2030437004 @default.
- W1563368481 cites W2031904472 @default.
- W1563368481 cites W2036278472 @default.
- W1563368481 cites W2036791731 @default.
- W1563368481 cites W2037598248 @default.
- W1563368481 cites W2039366912 @default.
- W1563368481 cites W2044416918 @default.
- W1563368481 cites W2044931258 @default.
- W1563368481 cites W2047284146 @default.
- W1563368481 cites W2048217371 @default.
- W1563368481 cites W2050299142 @default.
- W1563368481 cites W2061123442 @default.
- W1563368481 cites W2064998085 @default.
- W1563368481 cites W2066243395 @default.
- W1563368481 cites W2069580354 @default.
- W1563368481 cites W2072591046 @default.
- W1563368481 cites W2079153699 @default.
- W1563368481 cites W2083776823 @default.
- W1563368481 cites W2084719333 @default.
- W1563368481 cites W2084873710 @default.
- W1563368481 cites W2085386757 @default.
- W1563368481 cites W2085721778 @default.
- W1563368481 cites W2087838091 @default.
- W1563368481 cites W2093657982 @default.
- W1563368481 cites W2094760170 @default.
- W1563368481 cites W2105348198 @default.
- W1563368481 cites W2105510993 @default.
- W1563368481 cites W2111858259 @default.
- W1563368481 cites W2124636127 @default.
- W1563368481 cites W2138289499 @default.
- W1563368481 cites W2151219509 @default.
- W1563368481 cites W2151667261 @default.
- W1563368481 cites W2153754246 @default.
- W1563368481 cites W2158046987 @default.
- W1563368481 cites W2158547866 @default.
- W1563368481 cites W2170317460 @default.
- W1563368481 cites W2317425102 @default.
- W1563368481 cites W2330066395 @default.
- W1563368481 cites W2497007159 @default.
- W1563368481 cites W2949338118 @default.
- W1563368481 cites W2950429294 @default.
- W1563368481 cites W423201015 @default.
- W1563368481 doi "https://doi.org/10.1016/s0065-3160(06)41003-0" @default.
- W1563368481 hasPublicationYear "2006" @default.
- W1563368481 type Work @default.
- W1563368481 sameAs 1563368481 @default.
- W1563368481 citedByCount "6" @default.