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- W1563399264 abstract "Two‐color resonantly enhanced multiphoton ionization (REMPI) is used to study rotational autoionization of molecular hydrogen and nitric oxide. In contrast to conventional, single‐photon techniques, the REMPI technique can be used to study autoionizing levels of H2 that can decay only through very weak interactions such as p‐f mixing and singlet‐triplet mixing. In addition, rotational autoionization that occurs with that change in rotational quantum number greater than 2 can also be examined (i.e., ΔN+≳2). In homonuclear molecules, symmetry considerations require that ΔN+ be even; in heteronuclear molecules, ΔN+ may be even or odd. It is found, however, that NO is in some sense quasi‐homonuclear, and that processes with ΔN+ = even appear to be more efficient than processes with ΔN+ = odd." @default.
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- W1563399264 date "1989-01-01" @default.
- W1563399264 modified "2023-10-16" @default.
- W1563399264 title "Two-color studies of autoionizing states in small molecules" @default.
- W1563399264 doi "https://doi.org/10.1063/1.38658" @default.
- W1563399264 hasPublicationYear "1989" @default.
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