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- W1563566117 abstract "Low molecular weight gelators (LMWGs) are small molecules that are capable of entrapping solvents to form a gel in organic solvents or aqueous solution. These compounds rely solely on noncovalent forces to form the fibrous networks necessary to entrap a variety of solvents. The organogels and hydrogels thus formed could have applications in a variety of fields from environmental to biological to medicinal. Carbohydrates are ideal starting materials to synthesize LMWGs, because of their natural abundance, dense chirality, and biocompatibility. D-Glucose is the most common monosaccharide and D-glucosamine is isolated from natural sources, such as crab shells. Several series of compounds were synthesized using compounds 1-3 as the starting materials. These include esters, carbamates, amides, and ureas. The structure and gelation relationship was analyzed to obtain guidelines for designing new LMWGs. Compound 1 is a simple derivative of D-glucose and its terminal alkynyl esters and saturated carbamates are effective gelators. Compound 2 is a simple derivative of D-glucosamine and its amide and urea derivatives are also effective gelators. Compound 3 is formed from the deoxygenation of D-glucose. 1 O O HO OCH3 OH O Ph 2 O O HO OCH3 NH2 O Ph" @default.
- W1563566117 created "2016-06-24" @default.
- W1563566117 creator A5016338780 @default.
- W1563566117 date "2008-01-01" @default.
- W1563566117 modified "2023-09-27" @default.
- W1563566117 title "Glucose and glucosamine derivatives as novel low molecular weight gelators" @default.
- W1563566117 hasPublicationYear "2008" @default.
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