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• W1563792078 abstract "The reaction of alkyl-substituted (η5-CpR)(CO2) complexes with cobalt or nickel atoms in the presence of Cp★H or an arene has been shown to give homo- and heteronuclear M2- and M3-bridged metal carbonyl clusters. The crystal structures of the two homonuclear species obtained in the metal atom reactions, namely [(η6-mesitylene)Co]2CO(η-CpR) (μ3-CO)2 with R  Me5 or tBu2, have been determined. The electrochemical behaviour of the clusters [(η6-mesitylene)Co]2Co(η5CpR) (μ3-CO)2 (R  Me5, tBu2,iPr2) was studied by cyclic voltammetry and the results are discussed in detail. The reaction of (η5-CpMe)Mn(CO)3 with nickel atoms and Cp★H does not give heteronuclear MnNi cluster compounds, but instead the compound [(η5-Cp★)Ni]2Ni(η5-Cp)(μ3-CO)2." @default.
• W1563792078 created "2016-06-24" @default.
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• W1563792078 date "1994-04-01" @default.
• W1563792078 modified "2023-10-18" @default.
• W1563792078 title "Metal atoms in the synthesis of metal clusters" @default.
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• W1563792078 doi "https://doi.org/10.1016/0022-328x(94)80056-1" @default.
• W1563792078 hasPublicationYear "1994" @default.
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