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- W1563856051 abstract "以1-烯丙基-3-甲基咪唑盐酸盐([AMIM]Cl)作为离子液体单体,偶氮二异丁腈作为引发剂,二甲基亚砜为溶剂,实现了与丙烯腈(AN)在不同反应条件下的自由基共聚合.研究了AN/[AMIM]Cl二元共聚合的动力学,得到了相应的竞聚率数据(rAN=8.11,r[AMIM]Cl=0).用1H-NMR、GPC、DSC、TGA等手段对共聚物进行了表征.通过对AN/[AMIM]Cl二元共聚及AN/IA/[AMIM]Cl三元共聚的研究发现,[AMIM]Cl在与丙烯腈共聚时具有双重作用,一部分离子单体进入到共聚物的分子链中调节其亲水性及可纺性,剩下的大部分留在纺丝液中可显著降低纺丝液的黏度,从而使高分子量高固含量纺丝液的纺制成为可能,有望得到高性能的碳纤维原丝." @default.
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- W1563856051 date "2009-04-07" @default.
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- W1563856051 title "SOLUTION COPOLYMERIZATION OF ACRYLONITRILE WITH 1-ALLYL3-METHYL-IMIDAZOLIUM" @default.
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- W1563856051 doi "https://doi.org/10.3724/sp.j.1105.2009.00216" @default.
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