Matches in SemOpenAlex for { <https://semopenalex.org/work/W1563958986> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W1563958986 endingPage "18" @default.
- W1563958986 startingPage "12" @default.
- W1563958986 abstract "The [MgBr]+ salts of the μ4-S-containing double-butterfly anions {(μ-RS)(μ-CO)[Fe2(CO)6]2(μ4-S)}− (1, R=Ph, p-MeC6H4) react in situ with CS2 followed by treatment of the corresponding intermediate [MgBr]+ salts of anions {(μ-RS)(μ-SCS)[Fe2(CO)6]2(μ4-S)}− (m1) with ClCH2CO2Et to give μ4-S-containing double-butterfly iron carbonyl complexes (μ-RS)(μ-EtO2CCH2SCS)[Fe2(CO)6]2(μ4-S) (2a, R=Ph; 2b, R=p-MeC6H4), whereas the in situ reaction of the [MgX]+ (X=I, Br) salts of anions 1 (R=Me, Et) with μ-S2Fe2(CO)6 followed by treatment of the corresponding intermediate salts of anions {(μ-RS)(μ-S)[Fe2(CO)6]3(μ4-S)2}− (m2) with PhC(O)Cl produces μ4-S-containing unsymmetrical triple-butterfly iron carbonyl complexes (μ-RS)[μ-PhC(O)S][Fe2(CO)6]3(μ4-S)2 (3a, R=Me; 3b, R=Et). More interestingly, the symmetrical μ4-S-containing triple-butterfly complexes (μ-RE)2[Fe2(CO)6]3(μ4-S)2 (5a, RE=EtS; 5b, RE=t-BuS; 5c, RE=PhSe; 5d, RE=p-MeC6H4Se) can be synthesized by reaction of an excess of the [Et3NH]+ salts of the μ-CO-containing single-butterfly anions [(μ-RE)(μ-CO)Fe2(CO)6]− (4) with μ-S2Fe2(CO)6 and subsequent treatment of the resulting mixture with SO2Cl2. While the function of an excessive 4 for production of 5a–d is proposed, products 2a,b, 3a,b and 5a–d have been characterized by elemental analysis, and IR and 1H NMR spectroscopy, as well as for 3b and 5b by X-ray diffraction techniques." @default.
- W1563958986 created "2016-06-24" @default.
- W1563958986 creator A5011116151 @default.
- W1563958986 creator A5016909344 @default.
- W1563958986 creator A5050187057 @default.
- W1563958986 creator A5058562954 @default.
- W1563958986 creator A5081385630 @default.
- W1563958986 date "2003-03-01" @default.
- W1563958986 modified "2023-10-18" @default.
- W1563958986 title "Synthesis and characterization of μ4-S-containing double- and triple-butterfly iron carbonyl complexes." @default.
- W1563958986 cites W1559787262 @default.
- W1563958986 cites W1583505201 @default.
- W1563958986 cites W1967729189 @default.
- W1563958986 cites W1990493132 @default.
- W1563958986 cites W2020930079 @default.
- W1563958986 cites W2021800863 @default.
- W1563958986 cites W2030275737 @default.
- W1563958986 cites W2055754123 @default.
- W1563958986 cites W2059724099 @default.
- W1563958986 cites W2060859846 @default.
- W1563958986 cites W2148278945 @default.
- W1563958986 cites W2324712656 @default.
- W1563958986 cites W2325390765 @default.
- W1563958986 cites W2329167843 @default.
- W1563958986 cites W4243399029 @default.
- W1563958986 doi "https://doi.org/10.1016/s0020-1693(02)01382-8" @default.
- W1563958986 hasPublicationYear "2003" @default.
- W1563958986 type Work @default.
- W1563958986 sameAs 1563958986 @default.
- W1563958986 citedByCount "5" @default.
- W1563958986 countsByYear W15639589862013 @default.
- W1563958986 crossrefType "journal-article" @default.
- W1563958986 hasAuthorship W1563958986A5011116151 @default.
- W1563958986 hasAuthorship W1563958986A5016909344 @default.
- W1563958986 hasAuthorship W1563958986A5050187057 @default.
- W1563958986 hasAuthorship W1563958986A5058562954 @default.
- W1563958986 hasAuthorship W1563958986A5081385630 @default.
- W1563958986 hasConcept C155647269 @default.
- W1563958986 hasConcept C185592680 @default.
- W1563958986 hasConcept C71240020 @default.
- W1563958986 hasConcept C8010536 @default.
- W1563958986 hasConceptScore W1563958986C155647269 @default.
- W1563958986 hasConceptScore W1563958986C185592680 @default.
- W1563958986 hasConceptScore W1563958986C71240020 @default.
- W1563958986 hasConceptScore W1563958986C8010536 @default.
- W1563958986 hasLocation W15639589861 @default.
- W1563958986 hasOpenAccess W1563958986 @default.
- W1563958986 hasPrimaryLocation W15639589861 @default.
- W1563958986 hasRelatedWork W1531601525 @default.
- W1563958986 hasRelatedWork W2319480705 @default.
- W1563958986 hasRelatedWork W2384464875 @default.
- W1563958986 hasRelatedWork W2606230654 @default.
- W1563958986 hasRelatedWork W2607424097 @default.
- W1563958986 hasRelatedWork W2748952813 @default.
- W1563958986 hasRelatedWork W2899084033 @default.
- W1563958986 hasRelatedWork W2948807893 @default.
- W1563958986 hasRelatedWork W4387497383 @default.
- W1563958986 hasRelatedWork W2778153218 @default.
- W1563958986 hasVolume "346" @default.
- W1563958986 isParatext "false" @default.
- W1563958986 isRetracted "false" @default.
- W1563958986 magId "1563958986" @default.
- W1563958986 workType "article" @default.