Matches in SemOpenAlex for { <https://semopenalex.org/work/W1564174399> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W1564174399 endingPage "1485" @default.
- W1564174399 startingPage "1480" @default.
- W1564174399 abstract "Decarboxylated S-adenosyl-L-methionine and its nine analogs have been prepared by a modified method of Jamieson including alkylation of the appropriate aminoalkyl-adenosyl thioether with alkyl iodides in a mixture of formic and acetic acids in the presence of silver perchlorate. The use of silver perchlorate allowed various combinations of the thioether and the alkyl iodide, and prompted the reaction. The sulfonium compounds were obtained as a white hygroscopic powder in 99% ethanol after purification by silica gel column chromatography with a solvent system of butanol-acetic acid-water (1 : 1 : 1). The chemical and physical data of the sulfonium compounds supported a general structure containing 2 mol of sulfuric acid and 0.5 mol of ethanol. The nuclear magnetic resonance data showed the existence of sulfonium diastereoisomers." @default.
- W1564174399 created "2016-06-24" @default.
- W1564174399 creator A5016101027 @default.
- W1564174399 creator A5050903496 @default.
- W1564174399 creator A5074042118 @default.
- W1564174399 date "1978-01-01" @default.
- W1564174399 modified "2023-09-27" @default.
- W1564174399 title "Improved synthesis of decarboxylated S-adenosylmethionine and related sulfonium compounds." @default.
- W1564174399 doi "https://doi.org/10.1248/cpb.26.1480" @default.
- W1564174399 hasPublicationYear "1978" @default.
- W1564174399 type Work @default.
- W1564174399 sameAs 1564174399 @default.
- W1564174399 citedByCount "36" @default.
- W1564174399 countsByYear W15641743992012 @default.
- W1564174399 countsByYear W15641743992020 @default.
- W1564174399 crossrefType "journal-article" @default.
- W1564174399 hasAuthorship W1564174399A5016101027 @default.
- W1564174399 hasAuthorship W1564174399A5050903496 @default.
- W1564174399 hasAuthorship W1564174399A5074042118 @default.
- W1564174399 hasBestOaLocation W15641743991 @default.
- W1564174399 hasConcept C145148216 @default.
- W1564174399 hasConcept C161790260 @default.
- W1564174399 hasConcept C164361826 @default.
- W1564174399 hasConcept C178790620 @default.
- W1564174399 hasConcept C185592680 @default.
- W1564174399 hasConcept C2776371256 @default.
- W1564174399 hasConcept C2776673659 @default.
- W1564174399 hasConcept C2777040163 @default.
- W1564174399 hasConcept C2777379063 @default.
- W1564174399 hasConcept C2778870691 @default.
- W1564174399 hasConcept C2779444094 @default.
- W1564174399 hasConcept C2779532046 @default.
- W1564174399 hasConcept C2780263894 @default.
- W1564174399 hasConcept C2780471494 @default.
- W1564174399 hasConcept C2780709120 @default.
- W1564174399 hasConcept C51724486 @default.
- W1564174399 hasConceptScore W1564174399C145148216 @default.
- W1564174399 hasConceptScore W1564174399C161790260 @default.
- W1564174399 hasConceptScore W1564174399C164361826 @default.
- W1564174399 hasConceptScore W1564174399C178790620 @default.
- W1564174399 hasConceptScore W1564174399C185592680 @default.
- W1564174399 hasConceptScore W1564174399C2776371256 @default.
- W1564174399 hasConceptScore W1564174399C2776673659 @default.
- W1564174399 hasConceptScore W1564174399C2777040163 @default.
- W1564174399 hasConceptScore W1564174399C2777379063 @default.
- W1564174399 hasConceptScore W1564174399C2778870691 @default.
- W1564174399 hasConceptScore W1564174399C2779444094 @default.
- W1564174399 hasConceptScore W1564174399C2779532046 @default.
- W1564174399 hasConceptScore W1564174399C2780263894 @default.
- W1564174399 hasConceptScore W1564174399C2780471494 @default.
- W1564174399 hasConceptScore W1564174399C2780709120 @default.
- W1564174399 hasConceptScore W1564174399C51724486 @default.
- W1564174399 hasIssue "5" @default.
- W1564174399 hasLocation W15641743991 @default.
- W1564174399 hasOpenAccess W1564174399 @default.
- W1564174399 hasPrimaryLocation W15641743991 @default.
- W1564174399 hasRelatedWork W2037150812 @default.
- W1564174399 hasRelatedWork W2037476431 @default.
- W1564174399 hasRelatedWork W2073415150 @default.
- W1564174399 hasRelatedWork W2118828761 @default.
- W1564174399 hasRelatedWork W2153998060 @default.
- W1564174399 hasRelatedWork W2172937759 @default.
- W1564174399 hasRelatedWork W2949203286 @default.
- W1564174399 hasRelatedWork W2951535388 @default.
- W1564174399 hasRelatedWork W2951884646 @default.
- W1564174399 hasRelatedWork W2952757874 @default.
- W1564174399 hasVolume "26" @default.
- W1564174399 isParatext "false" @default.
- W1564174399 isRetracted "false" @default.
- W1564174399 magId "1564174399" @default.
- W1564174399 workType "article" @default.