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- W1564801288 abstract "The use of gas-liquid chromatographic (GLC) retention indices for the determination of lipophilicity was studied for a series of alkyl and arylalkyl esters of substituted benzoic acids. The regression relationships between the logarithms of the partition coefficients and the retention characteristics measured on two cpillary columns, SE-30 and OV-351, were evaluated. The behaviour of arylalkyl esters and of alkyl esters cannot be expressed in terms of a single regression equation. This is probably a consequence of the effect of the intramolecular hydrophobic interaction upon the retention of arylalkyl esters under GLC conditions. An analysis of the isokinetic relationships revealed differences in the mechanisms of separation of these groups of esters." @default.
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- W1564801288 date "1987-01-01" @default.
- W1564801288 modified "2023-09-24" @default.
- W1564801288 title "Gas-liquid chromatography and lipophilicity of esters of benzoic acids" @default.
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- W1564801288 doi "https://doi.org/10.1016/s0021-9673(01)96494-5" @default.
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