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- W1564809063 abstract "The relationship between capacity factor (k′) and eluent composition for the C1C5 N-alkylbenzamides was not described adequately by either linear or quadratic equations. Using the chromatographic data determined in acetonitrile—water, the relationship between k′ and eluent composition was described by the solvophobi theory. Regression coefficients obtained from the solvophobic equation were used to calculated the contact surface area of the solute-bonded ligand complex. The theory was used to calculate k′ for each compound in a totally aqueous mobile phase. The results indicate that branched alkyl chains elute before their straight-chain analogues and among isomers the elution volume increases with the distance between the branching point and the amide nitrogen." @default.
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- W1564809063 date "1982-01-01" @default.
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- W1564809063 title "Investigation of N-alkylbenzamides by reversed-phase liquid chromatography" @default.
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- W1564809063 doi "https://doi.org/10.1016/s0021-9673(00)95788-1" @default.
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