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- W1565006399 abstract "Abstract : Whereas at least seven simple inorganic cations, NH3F+,1,2 NH2F2+,3 NF4+,4 N2F+,5 N2F3+,6 ONF2+,7 and N3NOF+,8 which contain N-F bonds, have been prepared and well characterized, the existence of corresponding N-Cl containing cations is not well established. Thus, only two N-Cl containing cations, NCl4+9 and ONCl2+,10,11 have been reported, however, our repeated attempts to duplicate their syntheses were unsuccessful, and the crystal structure, published for ONCl2+SbCl6-,10 has been challenged on theoretical grounds.12 The paucity of data on simple inorganic N-Cl containing cations can be attributed to the general explosiveness and instability of nitrogen chlorides.13-15 In this paper, the synthesis and characterization of NH3Cl+M- salts (M = BF4, AsF6, or SbF6), the first examples of compounds containing a stable, simple inorganic cation with an N-Cl bond, are reported." @default.
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- W1565006399 date "2004-05-21" @default.
- W1565006399 modified "2023-09-24" @default.
- W1565006399 title "The NH3Cl+ Cation" @default.
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