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• W1565063302 endingPage "30" @default.
• W1565063302 startingPage "1" @default.
• W1565063302 abstract "Esters, amides, amines, acetals, and peptides are important industrial chemicals. Production of these chemicals is based onmultistep processes using stoichiometric amounts of acid or base promoters and coupling reagents, and involves reactive intermediates derived from alcohols or acids (Scheme 1.1), which leads to very large amounts waste [1]. Controlling overoxidation of substrates in the synthetic methods of these products is a challenge, and hence stepwise syntheses are performed (see below) [2]. Thus, green processes that can circumvent stoichiometric reagents and the generation of reactive intermediates, such as acid chlorides, and directly deliver stable and useful industrial products, such as esters and amides, in an atom-economical, selective manner without producing waste are needed. Pincer ligands, that is, tridentate ligands that enforce meridional geometry upon complexation to transition metals, result in pincer complexes which possess a unique balance of stability versus reactivity [3]. Transition-metal complexes of bulky, electron-rich ‘‘pincer’’ ligands have found important applications in synthesis, bond activation, and catalysis [4, 5]. Among these, pincer complexes of iPr-PNP (2,6-bis-(di-iso-propylphosphinomethyl)pyridine), tBu-PNP (2,6-bis-(di-tert-butylphosphinomethyl)pyridine), and PNN ((2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine), PNN-BPy (6-di-tert-butylphosphinomethyl-2,2′-bipyridine) ligands exhibit diverse reactivity [6–8]. These bulky, electron-rich pincer ligands can stabilize coordinatively unsaturated complexes and participate in unusual bond activation and catalytic processes. In most processes, homogeneously catalyzed by metal complexes, the ligands, while imparting critical properties on the metal center, do not participate directly in bond-making and -breaking processes with the substrates. In recent years, complexes in which the ligands actively cooperate with the metal center in bondactivation processes have been developed [9]. We have devised novel catalytic systems based on pincer complexes in which the pincer ligands cooperate with the metal center in a synergistic manner and their interplay facilitates the chemical processes. The pincer complexes are based on new pyridineand acridine-type" @default.
• W1565063302 created "2016-06-24" @default.
• W1565063302 creator A5017298749 @default.
• W1565063302 creator A5081692819 @default.
• W1565063302 date "2014-05-14" @default.
• W1565063302 modified "2023-10-17" @default.
• W1565063302 title "Catalysis by Pincer Complexes: Synthesis of Esters, Amides, and Peptides" @default.
• W1565063302 cites W1495482938 @default.
• W1565063302 cites W1583034884 @default.
• W1565063302 cites W168920097 @default.
• W1565063302 cites W1964512540 @default.
• W1565063302 cites W1968346623 @default.
• W1565063302 cites W1973410603 @default.
• W1565063302 cites W1975506590 @default.
• W1565063302 cites W1978155954 @default.
• W1565063302 cites W1978571774 @default.
• W1565063302 cites W1979000530 @default.
• W1565063302 cites W1981249378 @default.
• W1565063302 cites W1983107490 @default.
• W1565063302 cites W1986190616 @default.
• W1565063302 cites W1988402636 @default.
• W1565063302 cites W1990637745 @default.
• W1565063302 cites W1994349633 @default.
• W1565063302 cites W1994628146 @default.
• W1565063302 cites W1994904386 @default.
• W1565063302 cites W1995555506 @default.
• W1565063302 cites W1998697301 @default.
• W1565063302 cites W1999086206 @default.
• W1565063302 cites W1999088495 @default.
• W1565063302 cites W2003943583 @default.
• W1565063302 cites W2006446936 @default.
• W1565063302 cites W2006863928 @default.
• W1565063302 cites W2007593351 @default.
• W1565063302 cites W2009626516 @default.
• W1565063302 cites W2009859514 @default.
• W1565063302 cites W2013613760 @default.
• W1565063302 cites W2014319623 @default.
• W1565063302 cites W2015214461 @default.
• W1565063302 cites W2017268899 @default.
• W1565063302 cites W2017717474 @default.
• W1565063302 cites W2019618352 @default.
• W1565063302 cites W2020078456 @default.
• W1565063302 cites W2023173466 @default.
• W1565063302 cites W2026440517 @default.
• W1565063302 cites W2027475453 @default.
• W1565063302 cites W2029883290 @default.
• W1565063302 cites W2031441457 @default.
• W1565063302 cites W2031734182 @default.
• W1565063302 cites W2031762952 @default.
• W1565063302 cites W2033020343 @default.
• W1565063302 cites W2033385316 @default.
• W1565063302 cites W2037906407 @default.
• W1565063302 cites W2039584058 @default.
• W1565063302 cites W2041719513 @default.
• W1565063302 cites W2042926180 @default.
• W1565063302 cites W2047475425 @default.
• W1565063302 cites W2048503721 @default.
• W1565063302 cites W2049863329 @default.
• W1565063302 cites W2050592102 @default.
• W1565063302 cites W2057016395 @default.
• W1565063302 cites W2057352330 @default.
• W1565063302 cites W2060879531 @default.
• W1565063302 cites W2061601428 @default.
• W1565063302 cites W2065922225 @default.
• W1565063302 cites W2066758344 @default.
• W1565063302 cites W2069137488 @default.
• W1565063302 cites W2072565033 @default.
• W1565063302 cites W2073669612 @default.
• W1565063302 cites W2076320031 @default.
• W1565063302 cites W2078507758 @default.
• W1565063302 cites W2078883222 @default.
• W1565063302 cites W2079805813 @default.
• W1565063302 cites W2080262597 @default.
• W1565063302 cites W2080921803 @default.
• W1565063302 cites W2082073280 @default.
• W1565063302 cites W2083006150 @default.
• W1565063302 cites W2087081982 @default.
• W1565063302 cites W2089400651 @default.
• W1565063302 cites W2090549185 @default.
• W1565063302 cites W2090574683 @default.
• W1565063302 cites W2092662468 @default.
• W1565063302 cites W2093739290 @default.
• W1565063302 cites W2095465812 @default.
• W1565063302 cites W2095480759 @default.
• W1565063302 cites W2096695871 @default.
• W1565063302 cites W2100605095 @default.
• W1565063302 cites W2107988377 @default.
• W1565063302 cites W2108958966 @default.
• W1565063302 cites W2109370481 @default.
• W1565063302 cites W2116667141 @default.
• W1565063302 cites W2116773965 @default.
• W1565063302 cites W2132287644 @default.
• W1565063302 cites W2134194234 @default.
• W1565063302 cites W2135045057 @default.
• W1565063302 cites W2136486055 @default.
• W1565063302 cites W2139083301 @default.
• W1565063302 cites W2142721328 @default.
• W1565063302 cites W2154157809 @default.

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