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• W1565402233 abstract "Anthracene, its alkyl derivatives, and alkenes have been found to undergo oxidation by the VvH2O2AcOH catalytic system via a polar mechanism involving the transfer of singlet dioxygen from H2O2 to the unsaturated substrate molecule. The vanadium (V) complex with a singlet dioxygen molecule as ligand was suggested to be the only oxidant species active in the reaction. The Vv(O2•−) complex radical was detected as the only paramagnetic species in the system. Unusual acceleration of the styrene oxidation caused by the 2,6-di-tert-butyl-4-methylphenol additive (BHT) was observed and attributed to lowering the concentration of the Vv(O2•−) complex radical, which is assumed to be an active reductant toward the Vv complex with singlet dioxygen." @default.
• W1565402233 created "2016-06-24" @default.
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• W1565402233 date "1998-07-01" @default.
• W1565402233 modified "2023-09-23" @default.
• W1565402233 title "Oxidations in the system. Evidence of vanadium (V) complexes with superoxide anion and singlet dioxygen molecule as ligands" @default.
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• W1565402233 doi "https://doi.org/10.1016/s0020-1693(98)00129-7" @default.
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