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- W1565451903 abstract "Abstract The phase diagram of the binary (C3H7)4NF-H2O system has been studied. Three polyhydrates, (C3H7)4NF·12H2O, (C3H7)4NF·11.5H2O and (C3H7)4NF·11H2O, which melt congruently at -5.1; -6.7; -7.8°C, respectively, were found in the system. A single crystal X-ray structure of the novel hydrate Pr4NF·11H2O is reported. The space group for the layered hydrate is orthorhombic Fddd with a = 7.649(2); b = 14.920(6); c = 43.61(2)A, z = 8, DC = 1.077 g · cm−3 (t = -50°C). The layers of water and those of cations (C3H7)4N+ are held together by electrostatic and van der Waals interactions. Water forms a double water-fluoride layer which consists of interconnected fragments 54." @default.
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- W1565451903 date "1997-11-01" @default.
- W1565451903 modified "2023-09-26" @default.
- W1565451903 title "Phase Diagram of the (C3H7)4NF-H2O System and Crystal Structure of the Layered (C3H7)4NF·11H2O Hydrate" @default.
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- W1565451903 doi "https://doi.org/10.1080/10610279708034947" @default.
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