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• W1565649518 startingPage "61" @default.
• W1565649518 abstract "The redox behaviour of the d8 complexes [M(CO)(PPh3)3]+ (M = Rh, Ir) was studied on platinum electrode in 1,2-dimethoxyethane by cyclic voltammetry, differential pulse voltammetry, and potentiostatic coulometry. The complexes show two reversible one-electron reductions consistent with the formation of the rare zerovalent M(CO)(PPh3)3 and the anionic [M(CO)(PPh3)3]− derivatives, respectively. The reduced species were characterized by ESR and IR spectroscopy. A significant feature is that the one-electron reduced intermediates, in spite of their radical nature, react very easily with molecules capable of reacting as proton rather than H-atom sources to give the hydride species HM(CO)(PPh3)3. A tentative interpretation of this behaviour is suggested." @default.
• W1565649518 created "2016-06-24" @default.
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• W1565649518 date "1983-04-01" @default.
• W1565649518 modified "2023-09-24" @default.
• W1565649518 title "Electrochemistry of coordination compounds" @default.
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• W1565649518 doi "https://doi.org/10.1016/s0022-328x(00)98652-2" @default.
• W1565649518 hasPublicationYear "1983" @default.
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