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- W1566011657 abstract "The non-Newtonian viscosity of atactic and syndiotactic polystyrenes from 200 to 300˚C temperature range at various pressures is described well using our recently proposed YDT (Yahsi-Dinc-Tav) and the Cross models [1]. The Pressure-Volume-Temperature (PVT) data of atactic and syndiotactic PSs are fitted to the Simha-Somcynsky equation of state (SS) [2], to calculate the characteristic parameters, such as P∗ V∗, T∗ and the hole fraction. The relationships among PVTh values are elucidated both with the Simha-Somcynsk y Hole Theory and the previously obtained various Tait equations. The application of the linear dependency of our derived quantities; zero shear and constant shear-rate viscosities with hand Tdependent “thermo-occupancy” function (Yh) leads to extract novel conclusions on the differences between both types of PSs. In particular, as given in Figure 1, the viscoholibility (the derivative of the logarithm ofviscosities) decreases with the increasing hole fraction,h, computed from the SS theory." @default.
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- W1566011657 date "2015-01-30" @default.
- W1566011657 modified "2023-09-26" @default.
- W1566011657 title "EFFECT OF TACTICITY ON VISCOSITY-HOLE FRACTION BEHAVIOR OF ATACTIC AND SYNDIOTACTIC POLYSTYRENES" @default.
- W1566011657 doi "https://doi.org/10.18596/jotcsa.57327" @default.
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