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- W1566152661 abstract "Simultaneous SHG (second harmonic generation) and XRD (x-ray diffraction) capabilities have been developed at SSRL (Stanford Synchrotron Radiation laboratory) to examine the phase behavior of energetic materials, for example, HMX (octahydro- 1,3,5,7-tetranitro- 1,3,5,7-tetrmcine) and TATB (1,3,5-triamino-2,4,6 trinitrobenzene). This unique capability provides information on the evolution at the molecular level (centro and non-centrosymmetric) on material stability, phase transformation or decomposition reactions, which are important to continue refinement of computational predictions of material properties. This paper reports x-ray diffraction experiments on both HMX and TATB with increasing temperature and on simultaneous SHG and XRD experiments at fixed temperature. Our results indicate that, for HMX, the {beta} to {delta} transformation occurs over a range of temperature which do not correlate to the previously reported fast rise in SHG signal close to 17OOC as a phase transformation. No phase transition is observed for TATB, even though, previous paper shows an increase in the SHG signal." @default.
- W1566152661 created "2016-06-24" @default.
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- W1566152661 date "2001-06-19" @default.
- W1566152661 modified "2023-09-27" @default.
- W1566152661 title "Using Simultaneous SHG and XRD Capabilities to Examine Phase Transitions of HMX and TATB" @default.
- W1566152661 hasPublicationYear "2001" @default.
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