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• W1566177145 abstract "Infrared and Raman spectra of polycrystalline alkali metal-chromium (MCr(MoO4)2) and alkali metal-bismuth (MBi(MoO4)2) double molybdates were measured in the range 20–1000 cm−1 at room temperature. The distribution of vibrational levels was related to the results of unit-cell mode calculations. Factor group analysis has been performed to determine the symmetries and nature of the observed modes. Comparing the vibrational spectra of these compounds we conclude that the phonons above 250 cm−1 originate from internal molybdenum-oxygen vibrations and those under 250 cm−1 from external vibrations. The coordination around the molybdenum atom depends on the type of cation and changes from tetrahedral to octahedral." @default.
• W1566177145 created "2016-06-24" @default.
• W1566177145 creator A5012784505 @default.
• W1566177145 creator A5056546765 @default.
• W1566177145 date "1994-05-01" @default.
• W1566177145 modified "2023-10-18" @default.
• W1566177145 title "Vibrational properties of the double molybdates MX(MoO4)2 family (M = Li,Na,K,Cs; X = Bi,Cr)" @default.
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• W1566177145 doi "https://doi.org/10.1016/0924-2031(94)85044-5" @default.
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